Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2-Reference-Cited by-同舟云学术

Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2

Published:2017 Issue:62 Volume:53 Page:8664-8666
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Huh Daniel N.¹²³⁴^ORCID,Kotyk Christopher M.¹²³⁴^ORCID,Gembicky Milan⁵⁶⁷⁴^ORCID,Rheingold Arnold L.⁵⁶⁷⁴,Ziller Joseph W.¹²³⁴^ORCID,Evans William J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of California-Irvine

3. Irvine

4. USA

5. Department of Chemistry and Biochemistry

6. University of California-San Diego

7. La Jolla

Abstract

Ln²⁺-in-cryptand complexes (Ln = Sm, Eu, Yb) containing +2 ions surrounded only by neutral ligands are readily formed from silyl metallocenes.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC04396A

Reference30 articles.

1. Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State

2. Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]

3. Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln2+ Ions in the [K(2.2.2-cryptand)][(C5H4SiMe3)3Ln] Complexes: The Variable Nature of Dy2+ and Nd2+

4. Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+

5. Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States

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