Mechanochemical synthesis of mononuclear gold(i) halide complexes of diphosphine ligands with tuneable luminescent properties

Author:

Deák Andrea1ORCID,Jobbágy Csaba1,Demeter Attila2,Čelko Ladislav3,Cihlář Jaroslav3,Szabó Pál T.4ORCID,Ábrányi-Balogh Péter5ORCID,Crawford Deborah E.6,Virieux David7ORCID,Colacino Evelina7ORCID

Affiliation:

1. Supramolecular Chemistry Research Group, Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Eötvös Loránd Research Network (ELKH), Magyar Tudósok körútja 2, 1117 Budapest, Hungary

2. Renewable Energy Research Group, Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Eötvös Loránd Research Network (ELKH), Magyar Tudósok körútja 2, 1117 Budapest, Hungary

3. Central European Institute of Technology, Brno University of Technology, Purkyňova 123, 61200 Brno, Czech Republic

4. Centre for Structure Study, Research Centre for Natural Sciences, Eötvös Loránd Research Network (ELKH), 1117 Budapest, Magyar Tudósok körútja 2, Hungary

5. Medicinal Chemistry Research Group, Institute of Organic Chemistry, Research Centre for Natural Sciences, Eötvös Loránd Research Network (ELKH), 1117 Budapest, Magyar Tudósok körútja 2, Hungary

6. School of Chemistry and Biosciences, University of Bradford Richmond Road, BD7 1DP, Bradford, UK

7. ICGM, Univ Montpellier CNRS, ENSCM, Montpellier, France

Abstract

A mechanochemical method was developed for the synthesis of Au(XantPhos)X (1: X = Cl; 2: X = I) and Au(N-XantPhos)Cl (3) complexes.

Funder

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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