Mechanochemical preparation of strongly emissive monosubstituted triarylphosphane gold(i) compounds activated by hydrogen bonding driven aggregations

Author:

Luciani Lorenzo1,Sargentoni Nicola1,Graiff Claudia2ORCID,Monge Miguel3ORCID,Rodríguez-Castillo María3ORCID,López-de-Luzuriaga José M.3ORCID,Galassi Rossana1ORCID

Affiliation:

1. University of Camerino, School of Science and Technology, Chemistry Division, c/o ChIP, Via Madonna delle Carceri, 10, Camerino, I-62032, Italy

2. Department of Chemistry, Life Sciences and Environmental Sustainability, Università degli Studi di Parma, Parco Area delle Scienze 17/A, Parma, I-43124, Italy

3. Universidad de La Rioja, Departamento de Química, Área de Química Inorgánica, Centro de Investigación en Síntesis Química, Complejo Científico-Tecnológico, Madre de Dios, 53, 26004 Logroño, La Rioja, Spain

Abstract

LAG mechanochemical methods are applied for the preparation of luminescent di- and tri-coordinated gold(i) derivatives. Among them, a distorted T shaped bis-phosphane gold(i) chloride compound strongly emits upon self-aggregation by hydrogen bonding.

Funder

Università degli Studi di Camerino

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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