Electronic structures and selective fluoride sensing features of Os(bpy)2(HL2−) and [{Os(bpy)2}2(μ-HL2−)]2+ (H3L: 5-(1H-benzo[d]imidazol-2-yl)-1H-imidazole-4-carboxylic acid)

Author:

Das Ankita123,Agarwala Hemlata123,Kundu Tanaya123,Ghosh Prabir123,Mondal Sudipta123,Mobin Shaikh M.4567,Lahiri Goutam Kumar123

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai-400076, India

4. Discipline of Chemistry

5. School of Basic Sciences

6. Indian Institute of Technology Indore

7. Indore 452017, India

Abstract

The non-innocence of coordinated HL2− in [(bpy)2Os(HL2−)]n (1n) and (2n) and their selectivity towards F recognition were evaluated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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