Variable electronic structure and spin distribution in bis(2,2′-bipyridine)-metal complexes (M = Ru or Os) of 4,5-dioxido- and 4,5-diimido-pyrene-Reference-Cited by-同舟云学术

Variable electronic structure and spin distribution in bis(2,2′-bipyridine)-metal complexes (M = Ru or Os) of 4,5-dioxido- and 4,5-diimido-pyrene

Published:2021 Issue:12 Volume:50 Page:4191-4201
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chatterjee Madhumita¹²³⁴,Mondal Sudipta⁵⁶⁷⁸,Hazari Arijit Singha¹²³⁴,Záliš Stanislav⁹¹⁰¹¹¹²,Kaim Wolfgang⁵⁶⁷⁸^ORCID,Lahiri Goutam Kumar¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai-400076

4. India

5. Institut für Anorganische Chemie

6. Universität Stuttgart

7. Stuttgart

8. Germany

9. J. Heyrovský Institute of Physical Chemistry

10. v.v.i.

11. Academy of Sciences of the Czech Republic

12. Czech Republic

Abstract

Electronic structure variation in metal/o-quinone orbital mixed systems [M(L)(bpy)₂]^x can be systematically effected by extending the π system (benzene/pyrene), by changing the donors (O/NH) and by substituting the metal centers (Ru/Os).

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

University Grants Commission

Baden-Württemberg Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00282A

Reference75 articles.

1. Catechol-quinone redox series involving bis(bipyridine)ruthenium(II) and tetrakis(pyridine)ruthenium(II)

2. Ruthenium Complexes of Quinone Related Ligands: A Study of the Electrochemical Properties of 2-Aminothiophenolatobis(2,2‘-Bipyridine)Ruthenium(II)

3. Ancillary Ligand Control of Electronic Structure in o-Benzoquinonediimine-Ruthenium Complex Redox Series: Structures, Electron Paramagnetic Resonance (EPR), and Ultraviolet−Visible−Near-Infrared (UV-vis-NIR) Spectroelectrochemistry

4. Substituent effects and bonding characteristics in (o-benzoquinone diimine)bis(bipyridine)ruthenium(II) complexes

5. Noninnocently Behaving Bridging Anions of the Widely Distributed Antioxidant Ellagic Acid in Diruthenium Complexes

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