Activation of DMSO(-d6) via heterogeneous photo-Fenton-like process with in situ production of hydroxyl radicals for the C–H (trideutero)methylation of (iso)quinoliniums-Reference-Cited by-同舟云学术

Activation of DMSO(-d₆) via heterogeneous photo-Fenton-like process with in situ production of hydroxyl radicals for the C–H (trideutero)methylation of (iso)quinoliniums

Published:2023 Issue:8 Volume:25 Page:3187-3197
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Natarajan Palani¹²^ORCID,Basak Aleyna¹³,Metin Onder¹⁴^ORCID

Affiliation:

1. Department of Chemistry, College of Sciences, Koç University, 34450, Sarıyer, Istanbul, Turkey

2. Department of Chemistry & Centre for Advanced Studies in Chemistry, Panjab University, Chandigarh - 160014, India

3. Graduate School of Sciences and Engineering, Koç University, 34450, Sarıyer, Istanbul, Turkey

4. Koç University Surface Science and Technology Center (KUYTAM), 34450, Sarıyer, Istanbul, Turkey

Abstract

All Fenton reagent-assisted DMSO activation and in situ ˙CH3-radical production reported yet exclusively employ homogeneous reagent systems. However, the method described herein is based on the use of a heterogeneous photo-Fenton-like system.

Funder

Türkiye Bilimsel ve Teknolojik Araştırma Kurumu

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC00187C

Reference45 articles.

1. The Methylation Effect in Medicinal Chemistry

2. Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions

3. The Importance of Being Me: Magic Methyls, Methyltransferase Inhibitors, and the Discovery of Tazemetostat