nBu2Sn(SnBu)2 and nBu3SnEnBu (E = S or Se) – effective single source precursors for the CVD of SnS and SnSe thermoelectric thin films

Author:

Robinson Fred1234ORCID,Curran Peter J.564,de Groot C. H. (Kees)7234ORCID,Hardie Duncan564,Hector Andrew L.1234ORCID,Holloway Katherine1234,Huang Ruomeng7234ORCID,Newbrook Daniel7234ORCID,Reid Gillian1234ORCID

Affiliation:

1. School of Chemistry

2. University of Southampton

3. Southampton SO17 1BJ

4. UK

5. Deregallera Ltd

6. Caerphilly CF83 3HU

7. School of Electronics and Computer Science

Abstract

LPCVD with the title compounds produces S-deficient SnS, or stoichiometric, semiconducting, resistive SnS or SnSe films with large positive Seebeck coefficients and an SnSe power factor of 0.4 μW cm−1 K−2 at 425 K.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

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