Highly efficient synthesis and stereoselective migration reactions of chiral five-membered aza-spiroindolenines: scope and mechanistic understanding-Reference-Cited by-同舟云学术

Highly efficient synthesis and stereoselective migration reactions of chiral five-membered aza-spiroindolenines: scope and mechanistic understanding

Published:2016 Issue:7 Volume:7 Page:4453-4459
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Qing-Feng¹²³⁴⁵,Zheng Chao¹²³⁴⁵,Zhuo Chun-Xiang¹²³⁴⁵,You Shu-Li¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. China

Abstract

Ir-catalyzed asymmetric allylic dearomatization affords five-membered aza-spiroindolenines, from which enantioenriched Pictet–Spengler-type products are obtained via a highly stereoselective migration.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00176A

Reference72 articles.

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