Nuclearity expansion in Pd clusters triggered by the migration of a phenyl group in cyclooligosilanes-Reference-Cited by-同舟云学术

Nuclearity expansion in Pd clusters triggered by the migration of a phenyl group in cyclooligosilanes

Published:2021 Issue:62 Volume:57 Page:7649-7652
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Shimamoto Kento¹²³⁴⁵,Sunada Yusuke¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry

2. School of Engineering

3. The University of Tokyo

4. 4-6-1

5. Komaba

Abstract

Heptanuclear palladium clusters were synthesized via the reaction of [Pd(CN^tBu)₂]₃ with Ph-substituted cyclooligosilanes. The generation of the SiPh moiety upon migration of a Ph group is the key to assembling the seven palladium atoms effectively.

Funder

Precursory Research for Embryonic Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC02682H

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3. Two-Dimensional (2D) Nanomaterials towards Electrochemical Nanoarchitectonics in Energy-Related Applications

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