Synthesis of a homoleptic tris(silylene)–palladium(0) complex and a silylyne-bridged tetranuclear palladium cluster-Reference-Cited by-同舟云学术

Synthesis of a homoleptic tris(silylene)–palladium(0) complex and a silylyne-bridged tetranuclear palladium cluster

Published:2023 Issue:65 Volume:59 Page:9844-9847
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sekiguchi Jueri¹,Kazama Yugo¹,Ishii Akihiko¹^ORCID,Nakata Norio¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama, 338-8570, Japan

Abstract

Ligand-exchange reactions of iminophosphonamido-chlorosilylene with palladium complexes afforded a homoleptic tris(silylene)palladium(0) or a μ3-silylyne-bridged palladium cluster.

Funder

Japan Society for the Promotion of Science

Iwatani Naoji Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02543H

Reference50 articles.

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5. Group 10 transition-metal complexes with metal–silicon bonds derived from 1,2-disilylbenzenes and bis(2-silylphenyl)silane

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