Modulation of the electronic structure of metallic bismuth catalysts by cerium doping to facilitate electrocatalytic CO2 reduction to formate

Author:

Zhang Yangyuan1,Liu Shilong1,Ji Nannan1,Wei Lingzhi1,Liang Qiyang1ORCID,Li Jiejie2,Tian Ziqi2ORCID,Su Jianwei1ORCID,Chen Qianwang3ORCID

Affiliation:

1. Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Anhui University, Hefei 230601, China

2. Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

3. Hefei National Laboratory for Physical Science at Microscale, Department of Materials Science & Engineering, University of Science and Technology of China, Hefei 230026, China

Abstract

Bi(0) metal was utilized as a CO2RR catalyst to achieve enhanced durability in cathodic applications. Besides, the CO2RR activity was effectively improved by a promising strategy of electronic structure modulation through Ce doping.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Ningbo Municipality

Natural Science Foundation of Anhui Province

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

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