Elevated reaction order of 1,3,5-tri-tert-butylbenzene bromination as evidence of a clustered polybromide transition state: a combined kinetic and computational study
Author:
Affiliation:
1. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
2. Siberian Branch of the Russian Academy of Sciences
3. Russian Federation
4. Novosibirsk State University
5. Department of Chemistry
6. Imperial College London
7. London
8. UK
Abstract
The kinetics and mechanism of concurrent bromo-de-protonation and bromo-de-tert-butylation of 1,3,5-tri-tert-butylbenzene at different bromine concentrations were studied experimentally and theoretically.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00607A
Reference45 articles.
1. Electrophilic Aromatic Substitution: New Insights into an Old Class of Reactions
2. Theoretical Investigation into Rate-Determining Factors in Electrophilic Aromatic Halogenation
3. Noncatalytic bromination of benzene: A combined computational and experimental study
4. A 50th Order Reaction Predicted and Observed for Sickle Hemoglobin Nucleation
5. Recent Discoveries of Polyhalogen Anions - from Bromine to Fluorine
Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Preparation, Aromaticity, and Bromination of Spiro Iridafurans;Inorganic Chemistry;2023-10-02
2. Photochemical radical benzylic bromination with Br2: Computational modeling of the mechanism and microkinetic;Computational and Theoretical Chemistry;2023-09
3. Friedel-Crafts Reaction: Theoretical Study of the Mechanism of Benzene Alkylation with Isopropyl Chloride Catalyzed by AlCl3 and Al2Cl6;Journal of the Brazilian Chemical Society;2022
4. Cluster halogenation of adamantane and its derivatives with bromine and iodine monochloride;Organic & Biomolecular Chemistry;2022
5. Computational NMR of charged systems;Magnetic Resonance in Chemistry;2021-09-08
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3