Cluster halogenation of adamantane and its derivatives with bromine and iodine monochloride-Reference-Cited by-同舟云学术

Cluster halogenation of adamantane and its derivatives with bromine and iodine monochloride

Published:2022 Issue:43 Volume:20 Page:8515-8527
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Shernyukov Andrey V.¹^ORCID,Salnikov George E.¹^ORCID,Krasnov Vyacheslav I.¹^ORCID,Genaev Alexander M.¹^ORCID

Affiliation:

1. N.N. Vorozhtsov Institute of Organic Chemistry, Pr. Ak. Lavrentieva 9, Novosibirsk 630090, Russia

Abstract

Noncatalytic halogenation of adamantane with Br2 or ICl proceeds according to the cluster mechanism featuring high kinetic order in halogen and a sharp decrease in DFT energy barrier when additional halogen molecules are involved in the system.

Funder

Russian Foundation for Basic Research

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01455F

Reference53 articles.

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