Direct hydrosilylation by a zirconacycle with β-hydrogen

Author:

Yan KaKing123,Pindwal Aradhana123,Ellern Arkady123,Sadow Aaron D.123

Affiliation:

1. Department of Chemistry

2. Iowa State University

3. Ames, USA

Abstract

The pendent β-SiH-containing zirconacycle and formaldehyde react to give a direct hydrosilylation product, similarly to the reaction of the non-classical zwitterionic compound.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference40 articles.

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2. J. P. Collman , L. S.Hegedus , J. R.Norton and R. G.Finke , Principles and Applications of Organotransition Metal Chemistry , University Science Books , Mill Valley, CA , 1987

3. On the Nature of Agostic Interactions in Transition-Metal Amido Complexes

4. Intermolecular β-Hydrogen Abstraction in Ytterbium, Calcium, and Potassium Tris(dimethylsilyl)methyl Compounds

5. Lewis Acid-Mediated β-Hydride Abstraction Reactions of Divalent M(C(SiHMe2)3)2THF2 (M = Ca, Yb)

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