Tweaking the bridge in metallocene Zr(<scp>iv</scp>)/W(<scp>iv</scp>) bimetallic hydrides-Reference-Cited by-同舟云学术

Tweaking the bridge in metallocene Zr(iv)/W(iv) bimetallic hydrides

Published:2023 Issue:2 Volume:52 Page:394-408
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fernando Selwin¹^ORCID,Landrini Martina²,Macchioni Alceo²^ORCID,Hughes David L.¹^ORCID,Budzelaar Peter H. M.³^ORCID,Rocchigiani Luca¹²^ORCID

Affiliation:

1. School of Chemistry, University of East Anglia, Norwich Research Park, NR47TJ, Norwich, UK

2. Department of Chemistry, Biology and Biotechnology and CIRCC, University of Perugia, I-06123, Perugia, Italy

3. Department of Chemistry, University of Naples Federico II, Via Cintia, I-80126, Naples, Italy

Abstract

σ-Bond metathesis between zirconocene cations and Cp2WH2 affords a bimetallic bridging hydride with an out of plane configuration and no M–M interaction. Small molecules react predominantly at the Zr-C bond in the absence of bimetallic cooperativity.

Funder

University of East Anglia

Ministero dell’Istruzione, dell’Università e della Ricerca

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03833A

Reference81 articles.

1. Transition metal complexes with bridging hydride ligands

2. Bimetallic cooperation across the periodic table

3. M.Navarro and J.Campos , in Advances in Organometallic Chemistry , Academic Press Inc. , 2021 , vol. 75 , pp. 95–148

4. Catalytic Applications of Early/Late Heterobimetallic Complexes

5. E.Bodio , M.Picquet and P.le Gendre , in Homo- and Heterobimetallic Complexes in Catalysis: Cooperative Catalysis , ed. P. Kalck , Springer International Publishing , Cham , 2015 , pp. 139–186