Anion polarizabilities in oxynitride glasses. Establishing a common optical basicity scale-Reference-Cited by-同舟云学术

Anion polarizabilities in oxynitride glasses. Establishing a common optical basicity scale

Published:2020 Issue:17 Volume:22 Page:9543-9560
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Möncke Doris¹²³⁴⁵^ORCID,Ali Sharafat⁵⁶⁷⁸^ORCID,Jonson Bo⁵⁶⁷⁸^ORCID,Kamitsos Efstratios I.¹²³⁴^ORCID

Affiliation:

1. Theoretical and Physical Chemistry Institute

2. National Hellenic Research Foundation

3. 11635 Athens

4. Greece

5. Linnæus University

6. Department of Built Environment and Energy Technology

7. 35195 Växjö

8. Sweden

Abstract

For oxynitrides, oxygen and nitrogen polarizabilities were separated. The optical basicity of the isoelectronic anions F⁻:O²⁻:N³⁻ varies as follows: Λ(MF_m) = 1/2Λ(M₂O_m) = 1/3Λ(M₃N_m).

Funder

Knowledge Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06930E

Reference135 articles.

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5. J. A. Duffy , Bonding, energy levels, and bands in inorganic solids , Longman , 1990

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