Dispersion, ionic bonding and vibrational shifts in phospho-aluminosilicate glasses-Reference-Cited by-同舟云学术

Dispersion, ionic bonding and vibrational shifts in phospho-aluminosilicate glasses

Published:2024 Issue:18 Volume:26 Page:13826-13838
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Grammes Thilo¹^ORCID,de Ligny Dominique²^ORCID,Mathew Dintu¹,Griebenow Kristin¹,Scheffler Franziska¹,Lindner Florian³,Aichele Claudia³,Dellith Jan³,van Wüllen Leo⁴,Kamitsos Efstratios I.⁵^ORCID,Brauer Delia S.¹^ORCID

Affiliation:

1. Otto Schott Institute of Materials Research, Friedrich Schiller University Jena, Lessingstr. 12 (AWZ), 07743 Jena, Germany

2. Institute of Glass and Ceramics, Department of Materials Science and Engineering, Friedrich Alexander University Erlangen Nuremberg, Martensstr. 5, 91058 Erlangen, Germany

3. Leibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, Germany

4. Institute of Physics, Augsburg University, Universitätsstr. 1, 86159 Augsburg, Germany

5. Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, 11635 Athens, Greece

Abstract

The average shift of high-frequency IR and Raman spectra, calculated as their centre of gravity (COG), correlates linearly with optical basicity and allows for estimating the average degree of covalent/ionic bonding by vibrational spectroscopy.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00685B

Reference87 articles.

1. Effect of the Na/K mixing on the structure and the rheology of tectosilicate silica-rich melts

2. S.Matthes , Mineralogie , Springer , 2nd edn, 1987

3. A study of SiO2 glass and supercooled liquid to 1950 K via high-temperature Raman spectroscopy

4. Amorphous Materials: An experimental study of phosphorous and aluminosilicate speciation in and partitioning between aqueous fluids and silicate melts determined in-situ at high temperature and pressure

5. B. O.Mysen and P.Richet , Developments in Geochemistry Volume 10 - Silicate Glasses and Melts , Elsevier , 1st edn, 2005