Understanding the effect of lattice polarisability on the electrochemical properties of lithium tetrahaloaluminates, LiAlX<sub>4</sub> (X = Cl, Br, I)-Reference-Cited by-同舟云学术

Understanding the effect of lattice polarisability on the electrochemical properties of lithium tetrahaloaluminates, LiAlX₄ (X = Cl, Br, I)

Published:2022 Issue:25 Volume:10 Page:13467-13475
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Flores-González Nicolás¹^ORCID,López Martí²^ORCID,Minafra Nicolò³,Bohnenberger Jan⁴,Viñes Francesc²^ORCID,Rudić Svemir⁵^ORCID,Krossing Ingo⁴,Zeier Wolfgang G.³^ORCID,Illas Francesc²^ORCID,Gregory Duncan H.¹^ORCID

Affiliation:

1. WestCHEM, School of Chemistry, University of Glasgow, Joseph Black Building, Glasgow G12 8QQ, UK

2. Departament de Ciència de Materials i Química Física & Institut de Química Teòrica i Computacional (IQTCUB), Universitat de Barcelona, C/Martí i Franquès 1, 08028 Barcelona, Spain

3. Institute for Inorganic and Analytical Chemistry, University of Münster, Correnstr. 39, 48149, Germany

4. Institut für Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF), Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany

5. ISIS Pulsed Neutron and Muon Source, STFC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK

Abstract

Lithium ion conductivity in haloaluminate solid electrolytes can be tuned by the softening of the anion sublattice via a judicious juggling of the migration activation energy, Ea and the Meyer–Neldel energy, Δ0.

Funder

European Cooperation in Science and Technology

Engineering and Physical Sciences Research Council

Science and Technology Facilities Council

Comisión Nacional de Investigación Científica y Tecnológica

Deutsche Forschungsgemeinschaft

Ministerio de Ciencia e Innovación

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry