Chiral bisoxazoline catalyzed decarboxylative aldol reactions between β-carbonyl acids and trifluoroacetaldehyde hemiacetals as well as trifluoroacetaldehyde: the mechanism, the origin of enantioselectivity and the role of a catalyst-Reference-Cited by-同舟云学术

Chiral bisoxazoline catalyzed decarboxylative aldol reactions between β-carbonyl acids and trifluoroacetaldehyde hemiacetals as well as trifluoroacetaldehyde: the mechanism, the origin of enantioselectivity and the role of a catalyst

Published:2018 Issue:18 Volume:5 Page:2692-2709
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Yan Chao-Xian¹²³⁴⁵,Zhou Pan-Pan¹²³⁴⁵^ORCID,Yang Fang-Ling¹²³⁴⁵,Wu Rui-Zhi¹²³⁴⁵,Yang Xing¹²³⁴⁵,Yang Fan¹²³⁴⁵,Shao Xiangfeng¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Applied Organic Chemistry

2. Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province

3. College of Chemistry and Chemical Engineering

4. Lanzhou University

5. Lanzhou 730000

Abstract

The role of a catalyst in the decarboxylative aldol reactions between β-carbonyl acids and trifluoroacetaldehyde hemiacetals as well as trifluoroacetaldehyde catalyzed by chiral bisoxazoline were unveiled theoretically.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00578H

Reference93 articles.

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2. T. Inokuma , Development of Novel Hydrogen-Bond Donor Catalysts , Springer , Japan , 2013

3. Current applications of organocatalysts in asymmetric aldol reactions: An update