Suppressing carboxylate nucleophilicity with inorganic salts enables selective electrocarboxylation without sacrificial anodes-Reference-Cited by-同舟云学术

Suppressing carboxylate nucleophilicity with inorganic salts enables selective electrocarboxylation without sacrificial anodes

Published:2021 Issue:37 Volume:12 Page:12365-12376
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Corbin Nathan¹,Yang Deng-Tao¹,Lazouski Nikifar¹,Steinberg Katherine¹^ORCID,Manthiram Karthish¹^ORCID

Affiliation:

1. Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA

Abstract

Selective electrocarboxylation of nucleophilically susceptible organic halides without sacrificial anodes is enabled by inorganic salt additives, which suppress the nucleophilicity of anions in the electrolyte.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02413B

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