Ionization of gold (γ-methoxy)vinyl complexes generates reactive gold vinyl carbene complexes
Author:
Affiliation:
1. French Family Science Center
2. Duke University
3. Durham
4. USA
Abstract
Highly reactive cationic gold vinyl carbene/allylic cation complexes are generated in solution via γ-ionization of gold vinyl complexes.
Funder
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01574D
Reference102 articles.
1. Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox
2. Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity
3. Gold and diazo reagents: a fruitful tool for developing molecular complexity
4. Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity
5. Catalytic Access to α-Oxo Gold Carbenes by N–O Bond Oxidants
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