Substituent Effects and the Mechanism of Gold to Alkene Benzylidene Transfer Employing a Gold Sulfonium Benzylide Complex
Author:
Affiliation:
1. Department of Chemistry, French Family Science Center, Duke University, Durham, North Carolina 27708, United States
Funder
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.2c00097
Reference63 articles.
1. Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition
2. Gold Carbene or Carbenoid: Is There a Difference?
3. Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox
4. Gold(I)-Catalyzed Intramolecular Cyclopropanation of Dienynes
5. Mechanism of the gold-catalyzed cyclopropanation of alkenes with 1,6-enynes
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1. Combining ligand-enhanced backdonation and steric shielding to stabilize a mono-substituted Au(i) carbene;Chemical Communications;2023
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