Novel mixed 1D–2D lanthanide coordination polymers based on p-sulfonatocalix[4]arene and 4,4′-bipyridine-N,N′-dioxide where p-sulfonatocalix[4]arene acts as a guest
Author:
Affiliation:
1. Centre for Supramolecular Chemistry Research
2. Department of Chemistry
3. University of Cape Town
4. Rondebosch, South Africa
Abstract
Two novel mixed 1D–2D coordination polymers based on 2D [Ln(4,4′-bpdo)2(NO3)2(H2O)2]+n sheets and 1D [Ln2(4,4′-bpdo)2(C4AS)(NO3)(H2O)9]n chains (Ln = Sm for 1 and Ln = Nd for 2) sustained by π⋯π interactions and lattice water facilitated hydrogen bonds have been established.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CE/C5CE00153F
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