Regulating the size and spatial distribution of Pd nanoparticles supported by the defect engineered metal–organic framework HKUST-1 and applied in the aerobic oxidation of cinnamyl alcohol

Author:

Guo Penghu1234,Fu Qi1234,Yildiz Ceylan1234,Chen Yen-Ting1234,Ollegott Kevin1234,Froese Christian12345,Kleist Wolfgang1234ORCID,Fischer Roland A.67894ORCID,Wang Yuemin1011124ORCID,Muhler Martin12345ORCID,Peng Baoxiang12345ORCID

Affiliation:

1. Laboratory of Industrial Chemistry

2. Ruhr-University Bochum

3. 44801e Bochum

4. Germany

5. Max Planck Institute for Chemical Energy Conversion

6. Chair of Inorganic and Metal-Organic Chemistry

7. Department of Chemistry

8. Technical University of Munich

9. 85748 Garching

10. Institute of Functional Interfaces

11. Karlsruhe Institute of Technology

12. 76344 Eggenstein-Leopoldshafen

Abstract

A series of novel Pd@DE-HKUST-1(Cu/Pd) catalysts with different pydc feeding ratios were successfully synthesized. The size regime and the spatial distribution of the Pd NPs can be controlled by the amount of framework incorporated pydc.

Funder

Horizon 2020

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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