Ruthenium(ii)-catalyzed regioselective direct C4- and C5-diamidation of indoles and mechanistic studies-Reference-Cited by-同舟云学术

Ruthenium(ii)-catalyzed regioselective direct C4- and C5-diamidation of indoles and mechanistic studies

Published:2021 Issue:34 Volume:12 Page:11427-11437
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Devkota Shreedhar¹^ORCID,Kim Suyeon²³^ORCID,Yoo Seok Yeol²³^ORCID,Mohandoss Sonaimuthu¹^ORCID,Baik Mu-Hyun³²^ORCID,Lee Yong Rok¹^ORCID

Affiliation:

1. School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea

2. Department of Chemistry, Korea Advanced Institute of Technology (KAIST), Daejeon 34141, Republic of Korea

3. Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea

Abstract

Ruthenium(ii)-catalyzed regioselective C4-/C5-diamidation of 3-carbonylindoles is described and a DFT study is conducted to understand the observed regioselectivity and the mechanism.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02138A

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