Scalable selective electrochemical oxidation of sulfides to sulfoxides

Author:

Fu Zi-Hao1,Tian Hao-Dong1,Ni Shao-Fei2,Wright James S.3ORCID,Li Ming1,Wen Li-Rong1ORCID,Zhang Lin-Bao1ORCID

Affiliation:

1. State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

2. Department of Chemistry, Shantou University, Shantou, Guangdong, 515063, P. R. China

3. Department of Chemistry, University of Surrey, Guildford GU2 7XH, Surrey, UK

Abstract

An electrochemical protocol for the selective oxidation of sulfides to sulfoxides has been developed in which NaCl plays a dual role: (1) as an electrolyte for the electrochemical transformations and (2) as a redox mediator to avoid oxidation of sensitive functional groups.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Science and Technology Support Plan for Youth Innovation of Colleges and Universities of Shandong Province of China

Society of Hong Kong Scholars

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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