P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels–Alder reactions towards ligand design and functionalisation

Author:

Möller Tobias12345,Wonneberger Peter12345,Sárosi Menyhárt B.12345,Coburger Peter12345,Hey-Hawkins Evamarie12345

Affiliation:

1. Universität Leipzig

2. Faculty of Chemistry and Mineralogy

3. Institute of Inorganic Chemistry

4. D-04103 Leipzig

5. Germany

Abstract

A building set for chiral phosphorus. The principle of stereotopic face differentiation is successfully applied to a PC bond. A divergent ligand synthesis is feasible after reduction of the chiral auxiliary.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference58 articles.

1. Asymmetric hydrogenation

2. Asymmetric hydrogenation with a complex of rhodium and a chiral bisphosphine

3. Asymmetric hydrogenation. Rhodium chiral bisphosphine catalyst

4. Asymmetric Synthesis – The Essentials, ed. M. Christmann and S. Bräse, Wiley-VCH, Weinheim, 2nd edn, 2007

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