Synthesis of P-stereogenic 1-phosphanorbornane-derived phosphine–phosphite ligands and application in asymmetric catalysis

Author:

Ramazanova Kyzgaldak1ORCID,Chakrabortty Soumyadeep2ORCID,Müller Bernd H.2,Lönnecke Peter1ORCID,de Vries Johannes G.2ORCID,Hey-Hawkins Evamarie1ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany

2. Leibniz Institute for Catalysis e.V., Albert-Einstein-Strasse 29a, 18059 Rostock, Germany

Abstract

A convenient synthesis of enantiopure mixed donor phosphine–phosphite ligands has been developed incorporating P-stereogenic phosphanorbornane and axially chiral bisnaphthols into one ligand structure.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference39 articles.

1. Phosphorus(iii) Ligands in Homogeneous Catalysis: Design and Synthesis , ed. P. C. Kamer and P. W. van Leeuwen , John Wiley & Sons , 2012

2. Comprehensive Asymmetric Catalysis , ed. E. N. Jacobsen , A. Pfaltz and H. Yamamoto , Springer Science & Business Media , Berlin, Heidelberg , 2003

3. Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications , ed. A. Börner , Wiley-VCH , Weinheim , vol. 1–3 , 2008

4. Asymmetric hydrogenation with a complex of rhodium and a chiral bisphosphine

5. Asymmetric synthesis of organophosphorus compounds using H–P reagents derived from chiral alcohols

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1. 1-Phosphanorbornane aldehyde as precursor for enantiopure P,N,N ligands;Phosphorus, Sulfur, and Silicon and the Related Elements;2024-04-02

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