Direct oxidation of bromo-derived Fischer–Borsche oxo-ring using molecular iodine with combined experimental and computational study-Reference-Cited by-同舟云学术

Direct oxidation of bromo-derived Fischer–Borsche oxo-ring using molecular iodine with combined experimental and computational study

Published:2022 Issue:29 Volume:20 Page:5726-5729
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Humne Vivek T.¹^ORCID,Ghom Monica H.²,Naykode Mahavir S.²,Dangat Yuvraj³,Vanka Kumar³^ORCID,Lokhande Pradeep²

Affiliation:

1. Department of Chemistry, Shri. R. R. Lahoti Science College, Morshi, MS, India

2. Department of Chemistry, Savitribai Phule Pune University, Pune, MS, India

3. Division of Physical Chemistry, CSIR-National Chemical Laboratory, Pune, MS, India

Abstract

A direct oxidation of the bromo-derived Fischer–Borsche oxo-ring leading to carbazolequinone using iodine has been reported. This method has been used for the synthesis of the murrayaquinone and its derivatives, with good to excellent yield.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00793B

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2. Total synthesis and study of 6-deoxyerythronolide B by late-stage C–H oxidation

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