Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation-Reference-Cited by-同舟云学术

Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation

Published:2014 Issue:64 Volume:50 Page:8900-8903
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Nakajima Kazunari¹²³⁴,Kitagawa Mai¹²³⁴,Ashida Yuya¹²³⁴,Miyake Yoshihiro¹²³⁴,Nishibayashi Yoshiaki¹²³⁴

Affiliation:

1. Institute of Engineering Innovation

2. School of Engineering

3. The University of Tokyo

4. Tokyo, Japan

Abstract

We have succeeded in the visible light-mediated synthetic use of α-aminoalkyl radicals derived from α-silyl secondary amines toward addition to α,β-unsaturated carbonyl compounds. The resulting γ-aminocarbonyl compounds are converted into γ-lactams and pyrroles in a one-pot process.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC03000A

Reference42 articles.

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3. Chemistry and biology of non-tetramic γ-hydroxy-γ-lactams and γ-alkylidene-γ-lactams from natural sources

4. Preparation of chiral 4-substituted γ-lactams and the corresponding γ-aminobutyric acids. (Review)

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