Aminomethylations of electron-deficient compounds—bringing iron photoredox catalysis into play-Reference-Cited by-同舟云学术

Aminomethylations of electron-deficient compounds—bringing iron photoredox catalysis into play

Published:2024 Issue:30 Volume:15 Page:12077-12085
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ilic Aleksandra¹^ORCID,Strücker Benjamin R.¹,Johnson Catherine E.²^ORCID,Hainz Simon¹,Lomoth Reiner²^ORCID,Wärnmark Kenneth¹^ORCID

Affiliation:

1. Centre for Analysis and Synthesis (CAS), Department of Chemistry, Lund University, SE-22100 Lund, Sweden

2. Department of Chemistry-Ångström Laboratory, Uppsala University, SE-75120 Uppsala, Sweden

Abstract

Electron transfer to the 2LMCT state of a photoactive complex based on Earth-abundant iron has been used to drive photocatalytic aminomethylation reactions by generation of α-aminoalkyl radicals and the underlying mechanism has been investigated.

Funder

Sten K Johnsons stiftelse

Knut och Alice Wallenbergs Stiftelse

Vetenskapsrådet

Energimyndigheten

Stiftelsen för Strategisk Forskning

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02612H

Reference76 articles.

1. Generation and Alkylation of α-Carbamyl Radicals via Organic Photoredox Catalysis

2. Synthetic Utilization of α-Aminoalkyl Radicals and Related Species in Visible Light Photoredox Catalysis

3. Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds

4. Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts

5. Amine Functionalization via Oxidative Photoredox Catalysis: Methodology Development and Complex Molecule Synthesis