Switchable assembly of substituted pyrimidines and 2H-imidazoles via Cu(<scp>i</scp>)-catalysed ring expansion of 2 methoxyl-2H-azirines-Reference-Cited by-同舟云学术

Switchable assembly of substituted pyrimidines and 2H-imidazoles via Cu(i)-catalysed ring expansion of 2 methoxyl-2H-azirines

Published:2022 Issue:11 Volume:9 Page:3006-3011
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Sun Shaofa¹,Huang Jie¹^ORCID,Yuan Cheng¹,Wang Gangqiang¹²,Guo Donghui³,Wang Jian¹³^ORCID

Affiliation:

1. Hubei Key Laboratory of Radiation Chemistry and Functional Materials, Non-power Nuclear Technology Collaborative Innovation Center, School of Nuclear Technology and Chemistry & Biology, Hubei University of Science and Technology, Xianning, 437100, China

2. School of Pharmaceutical Sciences, South-Central MinZu University, Wuhan, 430074, China

3. School of Pharmaceutical Sciences, Tsinghua University, Beijing, 100084, China

Abstract

The unprecedented switchable synthesis of substituted pyrimidines and 2H-imidazoles via the Cu(i)-catalyzed ring expansion of 2-methoxyl-2H-azirines is described.

Funder

National Natural Science Foundation of China

Tsinghua University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00341D

Reference40 articles.

1. Synthesis of Oxygen- and Nitrogen-Containing Heterocycles by Ring-Closing Metathesis

2. Synthesis of 3,4,5-Trisubstituted-1,2,4-triazoles