A unified approach to mechanistic aspects of photochemical vapor generation-Reference-Cited by-同舟云学术

A unified approach to mechanistic aspects of photochemical vapor generation

Published:2019 Issue:4 Volume:34 Page:636-654
ISSN:0267-9477
Container-title:Journal of Analytical Atomic Spectrometry
language:en
Short-container-title:J. Anal. At. Spectrom.

Author:

Leonori Daniele¹²³⁴^ORCID,Sturgeon Ralph E.⁵⁶⁷⁸^ORCID

Affiliation:

1. School of Chemistry

2. University of Manchester

3. Manchester

4. UK

5. Chemical Metrology Group, Metrology

6. National Research Council of Canada

7. Ottawa

8. Canada

Abstract

A general model of redox reactions for PVG is proposed, driven by reducing radicals (e_(aq)⁻, H˙, R˙ and CO₂˙⁻) arising from concurrent VUV photolysis of carboxylic acids to yield the nascent elemental species which are subsequently attacked by H˙, H₃C˙, H⁺and CO to yield volatile products.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Spectroscopy,Analytical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/JA/C8JA00354H

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