Nickel-catalyzed cross-coupling of O,N-chelated diarylborinates with aryl chlorides and mesylates
Author:
Affiliation:
1. School of Chemistry & Molecular Engineering
2. East China University of Science & Technology
3. 130 Meilong Rd
4. Shanghai
5. China
Abstract
Practical nickel catalysis for efficient cross-coupling of O,N-chelated diarylborinates with aryl chlorides and mesylates based on air-stable yet readily activated organonickel precursor, trans-NiCl(Ph)(PPh3)2, and sterically unsymmetrical N-heterocyclic carbene in situ generated from imidazolium precursor with trihydrate potassium phosphate in toluene.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C8NJ05503C
Reference118 articles.
1. Organoboron Acids and Their Derivatives as Catalysts for Organic Synthesis
2. Catalysis Based on Reversible Covalent Interactions of Organoboron Compounds
3. Borinic Acid Catalyzed Stereo- and Regioselective Couplings of Glycosyl Methanesulfonates
4. Borinic acid-catalyzed stereo- and site-selective synthesis of β-glycosylceramides
5. Formamide Synthesis through Borinic Acid Catalysed Transamidation under Mild Conditions
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