Deciphering structural evolution of adsorbed ˙OH species on Zr-oxo nodes of UiO-66 to modulate methane hydroxylation-Reference-Cited by-同舟云学术

Deciphering structural evolution of adsorbed ˙OH species on Zr-oxo nodes of UiO-66 to modulate methane hydroxylation

Published:2024 Issue: Volume: Page:
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Tian Ling-Chan¹,Fang Geqian²³,Zhou Yun¹,Yu Wenjun²³,Li Lin²,Hu Jin-Nian¹,Wang Haiyan¹,Liang Jin-Xia¹^ORCID,Zhu Chun¹,Wang Xiaodong²^ORCID,Lin Jian²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Guizhou University, Guiyang, 550025, China

2. CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China

3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

The ˙OH quantity and DSOM performance on Zr-oxo nodes in the UiO-66-H catalyst exhibit a volcano-like curve relationship due to the evolution of p-band centers of O atoms on adsorbed oxygenic species.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Guizhou University

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Science Fund for Distinguished Young Scholars of Dalian Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA05851D