Titanium phosphonate oxo-alkoxide “clusters”: solution stability and facile hydrolytic transformation into nano titania-Reference-Cited by-同舟云学术

Titanium phosphonate oxo-alkoxide “clusters”: solution stability and facile hydrolytic transformation into nano titania

Published:2020 Issue:12 Volume:10 Page:6873-6883
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Svensson Fredric G.¹²³⁴,Daniel Geoffrey⁵²⁶⁴,Tai Cheuk-Wai⁷⁸⁹⁴^ORCID,Seisenbaeva Gulaim A.¹²³⁴^ORCID,Kessler Vadim G.¹²³⁴^ORCID

Affiliation:

1. Department of Molecular Sciences

2. Swedish University of Agricultural Sciences

3. 750 07 Uppsala

4. Sweden

5. Department of Biomaterials and Technology/Wood Science

6. 75007 Uppsala

7. Department of Materials and Environmental Chemistry

8. Stockholm University

9. 106 91 Stockholm

Abstract

Oligonuclear Ti(iv) oxo-alkoxide-phosphonate complexes, produced by reaction of tBuPO(OH)₂ with Ti(OR)₄, are easily topotactically hydrolyzed forming intricate nanostructures.

Funder

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/C9RA10691J

Reference58 articles.

1. Titanium oxo-clusters: precursors for a Lego-like construction of nanostructured hybrid materials

2. Hybrid Materials Based on the Embedding of Organically Modified Transition Metal Oxoclusters or Polyoxometalates into Polymers for Functional Applications: A Review

3. Cluster-based inorganic–organic hybrid materials

4. Solution equilibrium behind the room-temperature synthesis of nanocrystalline titanium dioxide

5. Mixed‐Ligand Titanium “Oxo Clusters”: Structural Insights into the Formation and Binding of Organic Molecules and Transformation into Oxide Nanostructures on Hydrolysis and Thermolysis

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