Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands
Author:
Affiliation:
1. Department of Inorganic Chemistry
2. Faculty of Science
3. Charles University in Prague
4. 12840 Prague 2
5. Czech Republic
6. Department of Physical and Macromolecular Chemistry
7. Department of Organic Chemistry
Abstract
Phosphinoferrocene carboxamides and thioamides coordinate “ligand-free” Cu(i) and Ag(i) ions in chelating manner to form hemilabile cationic bis-chelate or a unique ligand-bridged dimer.
Funder
Czech Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03279A
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4. Monomer, dimer or cyclic helicate? Coordination diversity with hard–soft P,N-donor ligands
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