Synthesis and reactivity of Pd(<scp>ii</scp>) imidoyl complexes obtained by insertion of isocyanoferrocene into the Pd–C bonds of orthopalladated precursors-Reference-Cited by-同舟云学术

登录注册会员服务联系我们

Synthesis and reactivity of Pd(ii) imidoyl complexes obtained by insertion of isocyanoferrocene into the Pd–C bonds of orthopalladated precursors

Published:2023 Issue:47 Volume:52 Page:17701-17710
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Franc Michal¹^ORCID,Vosáhlo Petr¹^ORCID,Schulz Jiří¹^ORCID,Císařová Ivana¹^ORCID,Štěpnička Petr¹^ORCID

Affiliation:

1. Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40, Prague, Czech Republic

Abstract

Insertion of isocyanoferrocene into Pd–C bonds of Pd(ii) complexes with cyclometallated ligands produced imidoyl complexes, which were converted into aminocarbene complexes. The imidoyl-to-carbene transformation changed the structure only marginally.

Funder

Grantová Agentura, Univerzita Karlova

Ministerstvo Školství, Mládeže a Tělovýchovy

Univerzita Karlova v Praze

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02717A

Reference78 articles.

1. A valence bond view of isocyanides' electronic structure

2. Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides

3. L.Malatesta , in Progr. Inorg. Chem , ed. F. A. Cotton , Interscience Publishers , London, UK , 1959 , vol. 1 , pp. 283–379

4. Aminocarbene complexes derived from nucleophilic addition to isocyanide ligands

5. Heterocyclic Carbenes: Synthesis and Coordination Chemistry

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370

www.globalauthorid.com

TOP