Thermal and photochemical control of nitro–nitrito linkage isomerism in single-crystals of [Ni(medpt)(NO2)(η2-ONO)]-Reference-Cited by-同舟云学术

Thermal and photochemical control of nitro–nitrito linkage isomerism in single-crystals of [Ni(medpt)(NO2)(η2-ONO)]

Published:2014 Issue:35 Volume:16 Page:8263-8271
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Hatcher Lauren E.¹²³,Bigos Edward J.¹²³,Bryant Mathew J.¹²³,MacCready Emily M.¹²³,Robinson Thomas P.¹²³,Saunders Lucy K.¹²³,Thomas Lynne H.¹²³,Beavers Christine M.⁴⁵⁶,Teat Simon J.⁴⁵⁶,Christensen Jeppe⁷⁸⁹,Raithby Paul R.¹²³⁷⁸

Affiliation:

1. Department of Chemistry

2. University of Bath

3. Bath, UK

4. Advanced Light Source

5. Lawrence Berkeley National Laboratory

6. Berkeley, USA

7. Research Complex at Harwell

8. Rutherford Appleton Laboratory

9. Didcot, UK

Abstract

[Ni(medpt)(NO₂)(η²-ONO)] displays an equilibrium between the η¹-NO₂ and the η¹-ONO linkage isomers between 150–298 K; upon photoactivation at 100 K the percentage of the η¹-ONO isomer increases.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CE/C4CE00675E

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