Very efficient organo-zinc scorpionates for CO<sub>2</sub>fixation into a variety of cyclic carbonates: synthesis, coordination ability and catalytic studies-Reference-Cited by-同舟云学术

Very efficient organo-zinc scorpionates for CO₂fixation into a variety of cyclic carbonates: synthesis, coordination ability and catalytic studies

Published:2023 Issue:18 Volume:52 Page:6105-6116
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Navarro Marta¹^ORCID,Garcés Andrés¹^ORCID,Sánchez-Barba Luis F.¹^ORCID,González-Lizana David¹,Lara-Sánchez Agustín²^ORCID

Affiliation:

1. Departamento de Biología y Geología, Física y Química Inorgánica, Universidad Rey Juan Carlos, Móstoles, 28933-Madrid, Spain

2. Universidad de Castilla-La Mancha, Departamento de Química Inorgánica, Orgánica y Bioquímica- Centro de Innovación en Química Avanzada (ORFEO-CINQA), Campus Universitario, 13071-Ciudad Real, Spain

Abstract

A series of [ZnMe(κ3-NNN′)] complexes combined with TBAB/TBAC show excellent performance (TOF up to 260 h−1) as catalysts for CO2fixation into cyclic carbonates under mild, solvent-free conditions, with good functional group tolerance.

Funder

Ministerio de Ciencia e Innovación

Junta de Comunidades de Castilla-La Mancha

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00510K

Reference72 articles.

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2. E.MacArthur , Completing the picture: How the circular economy tackles climate change, 2019 , https://ellenmacarthurfoundation.org/completing-the-picture

3. P. T.Anastas and J. C.Warner , Green chemistry: theory and practice , Oxford University Press , Oxford [England], New York , 1998

4. CO2-fixation into cyclic and polymeric carbonates: principles and applications

5. CO2Catalysis

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