Ion correlation and negative lithium transference in polyelectrolyte solutions-Reference-Cited by-同舟云学术

Ion correlation and negative lithium transference in polyelectrolyte solutions

Published:2023 Issue:24 Volume:14 Page:6546-6557
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bergstrom Helen K.¹²^ORCID,Fong Kara D.¹²^ORCID,Halat David M.¹³^ORCID,Karouta Carl A.¹³^ORCID,Celik Hasan C.⁴,Reimer Jeffrey A.¹³^ORCID,McCloskey Bryan D.¹²^ORCID

Affiliation:

1. Department of Chemical & Biomolecular Engineering, University of California, Berkeley, CA 94720, USA

2. Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

3. Materials Sciences Division, Joint Center for Energy Storage Research, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

4. College of Chemistry NMR Facility, University of California, Berkeley, CA, 94720, USA

Abstract

We demonstrate that contrary to previous reports, transference number decreases with increasing degree of polymerization in non-aqueous lithium-bearing polyelectrolyte solutions that have been proposed as next-generation battery electrolytes.

Funder

National Science Foundation

U.S. Department of Energy

National Institutes of Health

University of California Berkeley

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01224G

Reference53 articles.