Mechanistic study of carboxylic acid and phosphate ester cleavage by oximate metal complexes surpassing the limiting reactivity of highly basic free oximate anions-Reference-Cited by-同舟云学术

Mechanistic study of carboxylic acid and phosphate ester cleavage by oximate metal complexes surpassing the limiting reactivity of highly basic free oximate anions

Published:2020 Issue:8 Volume:49 Page:2452-2467
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lugo-González José Carlos¹²³⁴^ORCID,Gómez-Tagle Paola¹²³⁴^ORCID,Flores-Alamo Marcos¹²³⁴,Yatsimirsky Anatoly K.¹²³⁴^ORCID

Affiliation:

1. Universidad Nacional Autónoma de México

2. Facultad de Química

3. Mexico City

4. Mexico

Abstract

A family of oximate complexes of Zn(ii) and Cd(ii) with esterolytic reactivity surpassing the limiting reactivity of highly basic free oximates has been developed and mechanistically characterized.

Funder

Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04733F

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