Formation of uranium disulfide from a uranium thioamidate single-source precursor-Reference-Cited by-同舟云学术

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Formation of uranium disulfide from a uranium thioamidate single-source precursor

Published:2024 Issue:33 Volume:15 Page:13325-13332
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kelly Sheridon N.¹²^ORCID,Russo Dominic R.¹²,Ouellette Erik T.¹²^ORCID,Roy Debashree³,Swift Andrew J.⁴,Boreen Michael A.¹²^ORCID,Smith Patrick W.²,Moreau Liane M.³^ORCID,Arnold John¹²^ORCID,Minasian Stefan G.²^ORCID

Affiliation:

1. Department of Chemistry, University of California, Berkeley, CA 94720, USA

2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

3. Department of Chemistry, Washington State University, Pullman, WA 99164, USA

4. Physical and Life Sciences Directorate, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA

Abstract

A uranium (iv) thioamidate complex is used as a single-source precursor to uranium sulfide materials. Pyrolysis of the material yields crystalline γ-US2, an otherwise hard-to-obtain phase of the material.

Funder

Basic Energy Sciences

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03422H

Reference65 articles.

1. Sensing Electrons on the Edge

2. Calculated Bulk Properties of the Actinide Metals

3. Electronic structure and magnetism in actinide compounds

4. Advances in actinide thin films: synthesis, properties, and future directions

5. Orbital selective 5f electron character, indication of Kondo effect, and subatomic features of single uranium atoms

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