C–H reductive elimination during the reaction of cycloplatinated(ii) complexes with pyridine-2-thione: kinetic follow up-Reference-Cited by-同舟云学术

C–H reductive elimination during the reaction of cycloplatinated(ii) complexes with pyridine-2-thione: kinetic follow up

Published:2015 Issue:29 Volume:5 Page:22692-22702
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Aseman Marzieh Dadkhah¹²³⁴⁵,Nabavizadeh S. Masoud¹²³⁴⁵,Shahsavari Hamid R.¹⁶⁷⁵,Rashidi Mehdi¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. College of Sciences

3. Shiraz University

4. Shiraz 71467-13565

5. Iran

6. Institute for Advanced Studies in Basic Sciences

7. Zanjan

Abstract

Reactions of the cycloplatinated(ii) complexes [PtR(ppy)(SMe₂)], 1, where ppy = deprotonated 2-phenylpyridine and R = Me or p-MeC₆H₄, with pyridine-2-thione, C₅H₅SN, were studied by UV-vis and ¹H NMR spectroscopies and on the basis of the data a mechanism is proposed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA01341K

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