Discovery and mechanistic investigation of Pt-catalyzed oxidative homocoupling of benzene with PhI(OAc)2-Reference-Cited by-同舟云学术

Discovery and mechanistic investigation of Pt-catalyzed oxidative homocoupling of benzene with PhI(OAc)2

Published:2020 Issue:8 Volume:49 Page:2477-2486
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nabavizadeh S. Masoud¹²³⁴⁵^ORCID,Niroomand Hosseini Fatemeh²⁶⁷⁸⁵^ORCID,Park Chan⁹¹⁰¹¹¹¹¹²,Wu Guang⁹¹⁰¹¹¹¹¹²,Abu-Omar Mahdi M.⁹¹⁰¹¹¹¹¹²^ORCID

Affiliation:

1. Professor Rashidi Laboratory of Organometallic Chemistry

2. Department of Chemistry

3. College of Sciences

4. Shiraz University

5. Iran

6. Shiraz Branch

7. Islamic Azad University

8. Shiraz 71993-37635

9. Department of Chemistry and Biochemistry

10. University of California

11. Santa Barbara

12. USA

Abstract

Pt-catalyzed direct coupling of benzene to biphenyl using PhI(OAc)₂ as an oxidant in the absence of any acid as a co-solvent or co-catalyst was mechanistically investigated.

Funder

University of California, Santa Barbara

U.S. Department of Energy

Materials Research Science and Engineering Center, Harvard University

Shiraz University

Islamic Azad University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04261J

Reference39 articles.

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3. Double Deprotonation of Pyridinols Generates Potent Organic Electron-Donor Initiators for Haloarene-Arene Coupling

4. Highly Active Palladium-Based Catalyst System for the Aerobic Oxidative Direct Coupling of Benzene to Biphenyl

5. Direct aerobic oxidative homocoupling of benzene to biphenyl over functional porous organic polymer supported atomically dispersed palladium catalyst

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