A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO2/ethylene coupling-Reference-Cited by-同舟云学术

A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO2/ethylene coupling

Published:2017 Issue:2 Volume:8 Page:1463-1468
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Knopf Ioana¹²³⁴,Tofan Daniel¹²³⁴,Beetstra Dirk⁵⁶⁷⁸,Al-Nezari Abdulaziz⁵⁶⁷⁸,Al-Bahily Khalid⁵⁶⁷⁸,Cummins Christopher C.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Massachusetts Institute of Technology

3. Cambridge

4. USA

5. SABIC CRD

6. Fundamental Catalysis

7. Thuwal 23955-6900

8. Saudi Arabia

Abstract

The stereoselective synthesis of a family of cis-macrocyclic diphosphines was achieved in only three steps from white phosphorus and commercial materials. These new ligands showed activity in the nickel-catalyzed coupling of CO₂ and ethylene.

Funder

National Science Foundation

Saudi Basic Industries Corporation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC03614G

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