Aluminyl derived ethene functionalization with heteroallenes, leading to an intramolecular ligand rearrangement-Reference-Cited by-同舟云学术

Aluminyl derived ethene functionalization with heteroallenes, leading to an intramolecular ligand rearrangement

Published:2024 Issue:7 Volume:60 Page:881-884
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

O’Reilly Andrea¹^ORCID,Gardiner Michael G.²^ORCID,McMullin Claire L.³^ORCID,Fulton J. Robin¹^ORCID,Coles Martyn P.¹^ORCID

Affiliation:

1. School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington 6012, New Zealand

2. Research School of Chemistry, The Australian National University, Canberra, ACT 2601, Australia

3. Department of Chemistry, University of Bath, Bath, BA2 7AY, UK

Abstract

Functionalization of ethene as a component of an aluminacyclopropane has been achieved using heteroallenes (CO2, carbodiimide). A spontaneous ‘at metal’ ligand rearrangement occurs which alleviates steric congestion at the Al centre.

Funder

Marsden Fund

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05785B

Reference45 articles.

1. The Road Travelled: After Main‐Group Elements as Transition Metals

2. Main-group elements as transition metals

3. Recent advances in low oxidation state aluminium chemistry

4. The emerging chemistry of the aluminyl anion

5. The Aluminyl Anion: A New Generation of Aluminium Nucleophile

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Alumanyl Reduction, Reductive Coupling and C–H Isomerization of Organic Nitriles;Organometallics;2024-08-16

2. Mixing and matching N,N- and N,O-chelates in anionic Mg(i) compounds: synthesis and reactivity with RNCNR and CO;Chemical Communications;2024