Mixing and matching N,N- and N,O-chelates in anionic Mg(<scp>i</scp>) compounds: synthesis and reactivity with RNCNR and CO-Reference-Cited by-同舟云学术

Mixing and matching N,N- and N,O-chelates in anionic Mg(i) compounds: synthesis and reactivity with RNCNR and CO

Published:2024 Issue:56 Volume:60 Page:7204-7207
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

O'Reilly Andrea¹^ORCID,Haynes Matthew D.²^ORCID,Turner Zoë R.²^ORCID,McMullin Claire L.³^ORCID,Harder Sjoerd⁴^ORCID,O'Hare Dermot²^ORCID,Fulton J. Robin¹^ORCID,Coles Martyn P.¹^ORCID

Affiliation:

1. School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington 6012, New Zealand

2. Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK

3. Department of Chemistry, University of Bath, Bath, BA2 7AY, UK

4. Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universität, Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany

Abstract

Reduction of a bis(amidodimethyl)disiloxane Mg(ii) compound affords a mixture of N,N- and N,O-chelated Mg(i) species. Reactivity with RNCNR and CO demonstrate reducing behaviour, with the products showing a combination of ligands at magnesium.

Funder

Marsden Fund

Engineering and Physical Sciences Research Council

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02594F

Reference26 articles.

1. Stable Magnesium(I) Compounds with Mg-Mg Bonds

2. Dimeric magnesium(I) β-diketiminates: a new class of quasi-universal reducing agent

3. Stable dimeric magnesium(i) compounds: from chemical landmarks to versatile reagents

4. Alkaline earth metals: homometallic bonding

5. Synthesis and reactivity of low-oxidation-state alkaline earth metal complexes