Structural dynamics of a thermally silent triiron(<scp>ii</scp>) spin crossover defect grid complex-Reference-Cited by-同舟云学术

Structural dynamics of a thermally silent triiron(ii) spin crossover defect grid complex

Published:2023 Issue:35 Volume:52 Page:12224-12234
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Velazquez-Garcia Jose de Jesus¹^ORCID,Basuroy Krishnayan¹^ORCID,Storozhuk Darina¹^ORCID,Wong Joanne²,Demeshko Serhiy²,Meyer Franc²^ORCID,Henning Robert³,Techert Simone¹⁴^ORCID

Affiliation:

1. Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany

2. Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße, 4, 37077, Göttingen, Germany

3. Center for Advanced Radiation Sources, The University of Chicago, Argonne National Laboratory, 9700 South Cass Ave, Lemont, Illinois, 90439, USA

4. Institut für Röntgenphysik, Georg-August-Universität Göttingen, Friedrich-Hund-Platz 1, Göttingen, 37077, Germany

Abstract

A triiron(II) metallogrid was studied upon temperature increase and light irradiation. While lacking thermal spin transition, time-resolved photocrystallography revealed the photoinduced and elastic steps of the out-of-equilibrium dynamics.

Funder

National Institutes of Health

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02067C

Reference57 articles.

1. Thermal and Optical Switching of Iron(II) Complexes

2. P.Gütlich and H. A.Goodwin , Spin Crossover in Transition Metal Compounds I-III , Springer Berlin Heidelberg , Berlin, Heidelberg , 2004

3. Molecular spin crossover phenomenon: recent achievements and prospects

4. In memoriam of Professor John J. McGarvey

5. K. S.Murray , Spin–Crossover Materials , John Wiley & Sons, Ltd , 2013 , pp. 1–54

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