Out-of-equilibrium dynamics of a grid-like Fe(<scp>ii</scp>) spin crossover dimer triggered by a two-photon excitation-Reference-Cited by-同舟云学术

Out-of-equilibrium dynamics of a grid-like Fe(ii) spin crossover dimer triggered by a two-photon excitation

Published:2024 Issue:33 Volume:15 Page:13531-13540
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

de Jesus Velazquez-Garcia Jose¹^ORCID,Basuroy Krishnayan¹^ORCID,Wong Joanne²,Demeshko Serhiy²,Meyer Franc²^ORCID,Kim Insik³,Henning Robert³,Staechelin Yannic U.⁴^ORCID,Lange Holger⁵⁶^ORCID,Techert Simone¹⁷^ORCID

Affiliation:

1. Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany

2. Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße 4, Göttingen, 37077, Germany

3. Center for Advanced Radiation Sources, The University of Chicago, Argonne National Laboratory, 9700 South Cass Ave, Lemont, Illinois, 90439, USA

4. Institute of Physical Chemistry, Universität Hamburg, Martin-Luther-King-Platz 6, Hamburg, 20146, Germany

5. The Hamburg Center for Ultrafast Imaging, Universität Hamburg, 22761 Hamburg, Germany

6. Institute of Physics and Astronomy, Universität Potsdam, Karl-Liebknecht-Str. 24, 14476 Potsdam, Germany

7. Institut für Röntgenphysik, Georg-August-Universität Göttingen, Friedrich-Hund-Platz 1, Göttingen, 37077, Germany

Abstract

One-photon excitation (OPE) and two-photon excitation (TPE) were used to study the out-of-equilibrium dynamics in a spin crossover Fe(ii) dimer, revealing similar dynamics and a single molecular reorganization upon excitation with TPE.

Funder

Deutsche Forschungsgemeinschaft

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02933J

Reference69 articles.

1. P.Gütlich and H. A.Goodwin , Spin Crossover in Transition Metal Compounds I , Springer , 2004 , vol. 233 , pp. 1–47

2. Thermally and photo-induced spin crossover behaviour in an Fe(ii) imidazolylimine complex: [FeL3](ClO4)2

3. Thermal and Optical Switching of Iron(II) Complexes

4. Molecular spin crossover phenomenon: recent achievements and prospects

5. In memoriam of Professor John J. McGarvey